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55,80 €ISBN 978-3-8191-0387-2Softcover124 pages61 figures225 g24 x 17 cmEnglishThesis
December 2025
Oliver Khaled Salman
Modeling the Influence of Initiators on the High-Pressure LDPE Polymerization
This dissertation introduces a simulation model to describe the influence of initiator types in high-pressure autoclave reactors for LDPE production. The approach combines a deterministic model with a stochastic Monte Carlo model to simulate the polymerization process and to capture polymer properties such as molecular weight distribution and branching density. Mixing effects in the reactor are accounted through a compartmentalisation approach, enabling the simulation of temperature and concentration gradients. These gradients, which are mainly affected by the initiator type, reveal to describe the influence of the initiator onto the polymerization process and with this enables a link between the type of initiator and the properties of the resulting polymer.
Keywords: LDPE; Polymerreaktionstechnik; Simulation; Initiator
Darmstädter Schriftenreihe der Polymerisationstechnik
Edited by Prof. Dr. Markus Busch, Darmstadt
Volume 31
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