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48,80 €ISBN 978-3-8440-4525-3Softcover170 pages110 figures240 g21 x 14,8 cmEnglish-GermanThesis
June 2016
Madeleine Ecker
Lithium Plating in Lithium-Ion Batteries
An Experimental and Simulation Approach
The lifetime and safety of lithium-ion batteries is a key requirement for successful market introduction of electro mobility as well as for the application in stationary use. Lithium plating is an important effect in lithium-ion batteries, leading both to ageing as well as safety risks. The aim of this thesis is to achieve a better understanding of lithium plating using an experimental as well as a simulation approach. Experiments were performed on various types of lithium-ion batteries using changing operation conditions to gain knowledge of different influence factors on lithium plating. Post-mortem analysis was conducted on selected cells in order to examine the deposition process of metallic lithium. Furthermore, a physico-chemical model was developed and parameterised to simulate lithium plating and a validation is given by comparison with experimental data. The results illustrate impressively, how helpful a carefully parameterised physico-chemical model can be to design charging strategies as well as battery materials to prevent lithium plating.
Keywords: Lithium-Ionen Batterien; Lithium-Plating; Simulation; Parametrierung
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